On the enhanced corrosion resistance of elastomer-modified polybenzoxazine/graphene oxide nanocomposite coatings

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Eugene B. Caldona, Al Christopher C. de Leon, Joey D. Mangadlao, Kramer Joseph A. Lim, Bryan B. Pajarito, Rigoberto C. Advincula

2018 Reactive and Functional Polymers Vol. 123 Article Cited by 62 Quartile

Abstract

In this study, we demonstrate the use of rubber-modified polybenzoxazine (PBZ)/graphene oxide (GO) as a coating to protect carbon steel from corrosion. GO, acting as the nanofiller, is added in increasing amounts to enhance the barrier property of the resulting nanocomposite coatings. Results via immersion in chloride solution coupled with standard electrochemical measurements show that the rubber-modified PBZ is able to protect carbon steel from corrosion attack. Even more, the coatings containing small amounts of GO provided enhanced protective abilities for the carbon steel. By varying the amount of GO, the protective property is tuned and the optimum GO concentration that could offer the most enhanced corrosion resistance property is determined. © 2017 Elsevier B.V.

Affiliations

Department of Macromolecular Science and Engineering, Case Western Reserve University, Cleveland, 44106, OH, United States; Department of Chemical Engineering, University of the Philippines Diliman, Quezon City, 1101, Philippines; Department of Chemical Engineering, Saint Louis University, Baguio City, 2600, Philippines; Department of Chemical Engineering, University of San Carlos, Cebu City, 6000, Philippines